Determination of total sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry          下载免费PDF全文

Liu Bing-bing  Han Mei  Liu Jia  Jia Na  Zhang Chen-ling  Zhang Lin 《地下水科学与工程》2022,10(3):285-291

Sulfur speciation and concentration in geothermal water are of great significance for the research and utilization of the water resources. In most situations, it is necessary to determine the total sulfur in geothermal water. In this study, the method was established for the determination of determining total sulfur content — the inductively coupled plasma-atomic emission spectrometry (ICP-AES), with the wavelength of 182.034 nm selected in spectral line of sulfur. It was identified that the optimal working conditions of the ICP-AES instrument were 1 200 W for high frequency generator power 9 mm for vertical observation height, 0.30 MPa atomizer pressure, and 50 r/min analytical pump speed. The matrix interference of the method was eliminated by the matrix matching method. Using this method, sulfur detection limit and minimum quantitative detection limit were 0.028 mg/L and 0.110 mg/L, respectively, whilst the linear range was 0.0–100.0 mg/L. The recovery rate of sample was between 90.67% and 108.7%, and the relative standard deviation (RSD) was between 0.36% and 2.14%. The method was used to analyze the actual samples and the results were basically consistent with the industry standard method. With high analysis efficiency, the method has low detection limit and minimum quantitative detection limit, wide linear range, good precision and accuracy, and provides an important detection method for the determination of total sulfur in geothermal water.  相似文献   

塔里木盆地玉尓吐斯组高频层序沉积充填演化特征及控烃作用     

江维  高志前  胡宗全  赵永强  储呈林 《现代地质》2021,35(2):349-364

结合9个野外剖面和17口井,对塔里木盆地玉尔吐斯组沉积演化及其对烃源岩的制约作用进行了系统研究和分析。在精细对比后发现,塔里木盆地下寒武统玉尔吐斯组可分为2个三级层序(SQ1、SQ2)、5个四级层序(sq1—sq5),其中三级层序SQ1可分为3个四级层序,SQ2可分为2个四级层序。SQ1发生在寒武纪初期,海进速度较慢,影响范围相对局限,而SQ2的海进则相对迅速,影响范围较大。四级层序sq1发生在第一次海侵初期,水体浅,主要沉积紫红色白云岩、灰黑色砂屑白云岩,起填平补齐的作用;sq2、sq4发生在海侵—海退的转换时期,是两套深水的沉积,岩性以黑色泥岩、硅质泥岩和硅质岩为主,局部发育泥岩与条带状白云岩互层;sq3、sq5是海退过程中的浅水沉积,主要发育灰色白云岩和藻白云岩,局部有泥质夹层。利用Mn、Fe、Ti、Rb、K、Sr、Ba、Cu、U、V、Mo等元素及其比值进行沉积环境分析表明,sq2时期,水体深度大、盐度低、气候温暖湿润,有利于生物发育,并且其硫化缺氧的环境极其有利于有机质的保存;sq4时期,水体深度较大,盐度相对较小,气候相对温暖湿润,较为适合生物生存,并且其硫化缺氧夹次氧化的环境,较为适合有机质保存。高频海平面变化与沉积环境演化影响着玉尔吐斯组的烃源岩分布与品质,sq2时沉积的烃源岩品质优于sq4,但是其分布范围小于sq4。  相似文献   

储集层中高压流体引爆强地震的机理——以5.12汶川地震为例     

毛小平  何廉康  刘佳林  李岁岁  张学强  宿宇驰  卢鹏宇 《地质力学学报》2021,27(4):628-642

目前产生地震的机制仍以弹性回跳说为主:地震是因为断层错断使岩层的弹性能释放而引发。但越来越多的学者开始质疑,仅断层错断后的弹性能,是否真能达到实际地震所释放的巨大能量。因此,有必要探讨地震初动后破坏性强震的性质及其真正的能量来源。文章根据沉积地层中的储集层及其压力的特点分析得出,储集层内含有大量的高压流体,其压力在一定条件下可以释放出来,产生流体物理爆炸,有可能是强震能量的重要组成部分。通过计算得出,当断层破裂并刺穿面积较大的储集层时,其压力释放所产生的弹性能可以达到震级8.0以上地震所释放的能量;人为的工程活动也可引发小规模的流体压力的释放现象,如钻井时的井喷、水力压裂会诱发有感地震等。同时,文章根据对距离震中较近的地震台的波形及传播射线路径分析认为,强震波动可能不是横波S波,而是涨缩波P波,据此不能排除强震是由爆炸所致。综合汶川地震多个台站记录到的地震波的时间域和频率域特征、地面观测到的爆炸现象、地震后科学钻探获得的岩心等大量直接或间接证据,说明了这种流体爆炸能量释放的可能性。最后,文章提出了地震活动可分为三个阶段:微破裂阶段Ⅰ,该阶段有流体活动,并可产生动电效应,但未触发地震初动;地震初动后的断裂破裂阶段Ⅱ;由流体压力释放产生地震强震阶段Ⅲ。   相似文献   

基于不同邻近标签数选择的LANDMARC定位算法研究     

谢亚琴  王超 《南京气象学院学报》2019,11(5):621-624

对于基于射频识别的LANDMARC室内定位算法而言,该系统采用"k近邻"算法,通过选取k个与待测标签相邻且符合特定条件的参考标签,最后根据这些标签的位置结合权值估算出待测标签的坐标信息.但是在实际的操作过程中,最近邻参考标签数的选取无指导原则,具有一定的盲目性.针对这一问题,通过选取与待定位参考点最近邻的参考节点作为未知点,通过搜索法获得最优的邻近标签数k,在随后的未知节点的定位过程中,选取k个邻近标签进行定位.经过多次实验,最终得出结论,使用改进后的LANDMARC算法的性能要优于原来经典的LANDMARC算法,精确度提升了10%左右,同时避免了k值选取的盲目性.  相似文献   

基于秒级探空资料的中国地区浮力频率分布          下载免费PDF全文

李芳芳  陈起英  吴泓锟 《应用气象学报》2019,30(5):629-640

浮力频率用来描述大气层结稳定性,反映大气扰动强弱。利用2014年6月-2017年5月中国地区高垂直分辨率的秒级探空资料,分析了中国地区浮力频率的时空分布特征。结果表明:中国地区大气浮力频率总体随高度的增加而增大,低平流层值大于对流层值;对流层和低平流层中浮力频率随高度变化均较小可视为常数,过渡层浮力频率随高度变化较大,对流层中浮力频率受地形影响较平流层大。对流层中北方地区5 km高度以下的浮力频率随时间呈现出较弱的周期变化,周期为1年,峰值出现在冬季,南方地区随时间无明显变化;在过渡层中南北地区的浮力频率随时间均呈现出1年的周期变化,峰值出现在冬季,谷值出现在夏季;在低平流层中南北地区浮力频率随时间均无明显变化。浮力频率的大小变化对重力波参数有较大影响,秒级探空资料计算的的浮力频率和风速切变更精细,较常规探空资料更准确地反映大气稳定度的变化。  相似文献   

小尺度断裂沿层曲率敏感性研究     

胡建波 《地质与勘探》2023,59(4):891-900

沿层曲率作为地震属性的一种,不仅有数学几何意义更有着重要的地质意义。和相干体相比,沿层曲率在油气勘探中常被用于刻画地质构造形态及断裂精细解释,特别是在小尺度断裂发育的地区更为有效。而在实际工作中,有时利用沿层曲率所描述的断裂效果不太明显。为进一步明确对于刻画断裂结果的影响因素及其适用条件,以鄂尔多斯盆地Q区Tj9为研究对象,基于Geoeast软件对该区小尺度断裂系统从选取属性、方位角、频带三个方面展开分析。结果表明：（1）曲率比相干体更适用于刻画较小尺度的断层;（2）平面上从平行断裂的方位观测,断裂识别不清晰;从垂直断裂的方位观测,易于识别;（3）在反射层同相轴较强时,中高频段对断裂识别更清楚;在反射层同相轴较弱时,中频段对断裂识别更清楚。因此可以根据不同属性、不同方位角、不同频带对断裂的敏感程度,用不同的数据体解释小尺度断裂,提高对断层刻画的精度,为复杂油气勘探寻找有利区奠定基础。  相似文献   

浅地层剖面系统在福建沿海海底沉船调查中的应用     

李海东  胡毅  许江  林兆彬  刘伯然  王恒波  郑江龙 《海洋技术学报》2019,38(1)

海底沉船是水下文化遗产的一种重要类型和存在形式,利用综合地球物理手段对福建平潭、莆田及福州海域的海底沉船进行了探测研究,并重点探讨了不同浅地层剖面系统及不同探测频率在不同埋藏状态的水下文物调查中的应用。结果表明:浅地层剖面探测能够有效识别处于不同埋藏状态的沉船,尤其对探测埋藏海底面以下的沉船具有其他探测手段无法比拟的优势,但是探测频率的调节对目标物探测结果存在较大差异,对于埋藏式的海底沉船低频信号探测效果较理想。  相似文献   

Experimental study on wide-shallow composite bucket foundation for offshore wind turbine under cyclic loading     

Xuyue Wang  Hongyan Ding  Yonggang Liu 《Marine Georesources & Geotechnology》2019,37(1):1-13

As an appropriate type of foundation for offshore wind turbines (OWTs), wide-shallow composite bucket foundation (WSCBF) is cost-competitive, and it has a unique and special substructure that comprises seven internal rooms arranged in a honeycomb-like structure. In this study, the cyclic behavior of WSCBF for OWTs embedded in saturated clay was investigated using a large-scale model subjected to lateral cyclic loading. The responses of foundation under constant- and various-amplitude cyclic loadings were recorded in terms of displacements, rotations, and bending moments. The variations in stiffness and damping were obtained, and a collaborative bearing mechanical model between the bucket and soil was considered, which was beneficial for improving the stiffness of the whole structure. Accumulative deformation was found to have little effect on the bearing capacity of the foundation. Dynamic analysis in frequency domain was further performed on both moment and rotation data, and the complex, frequency-dependent impedance was also studied.  相似文献   

Uncertainty analysis of soil-pile interactions of monopile offshore wind turbine support structures     

《Applied Ocean Research》2019

The objective of this work is to study the uncertainties involved in the modelling of the soil-pile interaction concerning their influence on the prediction of the dynamic structural response of monopile offshore wind turbine support structures. Two main issues are identified and addressed: the adequacy of the method used to deal with the soil-pile interactions and the adequacy of the soil properties reflecting the behaviour of the soil. The present study develops an approach that defines the penetrated pile length depending on the soil profile. Also, a parameter is defined to avoid the excessive usage of steel for the penetrated pile structure. The uncertainties are included in the probabilistic free vibration analysis and the contribution of each random variable to the scatter of the response is estimated by performing a sensitivity analysis. The results indicate that the uncertainty involved in the modelling of the soil profile has a significant effect on the coefficient of variance of the natural frequency, which is a serious issue to be considered in the fatigue life assessment of offshore wind turbine support structures.  相似文献   

An ensemble approach for the analysis of extreme rainfall under climate change in Naples (Italy)     

Roberta Padulano  Alfredo Reder  Guido Rianna 《水文研究》2019,33(14):2020-2036

In the present paper, an ensemble approach is proposed to estimate possible modifications caused by climate changes in the extreme precipitation regime, with the rain gauge Napoli Servizio Idrografico (Naples, Italy) chosen as test case. The proposed research, focused on the analysis of extremes on the basis of climate model simulations and rainfall observations, is structured in several consecutive steps. In the first step, all the dynamically downscaled EURO‐CORDEX simulations at about 12 km horizontal resolution are collected for the current period 1971–2000 and the future period 2071–2100, for the RCP4.5 and the RCP8.5 concentration scenarios. In the second step, the significance of climate change effects on extreme precipitation is statistically tested by comparing current and future simulated data and bias‐correction is performed by means of a novel approach based on a combination of simple delta change and quantile delta mapping, in compliance with the storm index method. In the third step, two different ensemble models are proposed, accounting for the variabilities given by the use of different climate models and for their hindcast performances. Finally, the ensemble models are used to build novel intensity–duration–frequency curves, and their effects on the early warning system thresholds for the area of interest are evaluated.  相似文献